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If you have a food chain then the chain must have a beginning (where the food is made) and an end (where the food is finally all used up).
Thius in a food chain the "producers" of the food (the plants) are ALWAYS the start. The plants make food using CO2 from the air, Water from the ground and the energy they collect from Sunlight. It is the passing on of this energy from the Sun that is the chain.
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