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Well to understand this first you should know how a microwave oven works. A microwave oven works on the microwave frequency which is 2.45Ghz. Well this frequency is capable of heating water particles more because of the greater absorption factor.

The water particles in the food is heated which in turn heats the food in microwave oven.

Now lets take the case of 'egg'. The egg shell is made of calcium. The egg white have high quantity of water and the yolk contains fat.

When heated in a microwave, the temperature reaches a higher range exponentially and the water in albumin the egg white is vaporised. There is no escape of this expanded water. This leads to the explosion of egg.

Now in case of boiling water. There is no sudden rise in temperature, So there is even heating of the shell and the inside of egg. In this the calcium shell also expands a little because its contact with water. And the albumin doesn't reach high temperature like that in microwave.

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15y ago

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