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You may be thinking of Pero, Postum or Caffix. In addition there are several herbs ground and roasted, then served like or with coffee. Chickory root is an example of an herb used as a coffee extender from the Cajun tradition.

Here are some links with more information:

http://www.perous.com/

http://www.associatedcontent.com/article/703043/postum_coffee_substitute_dies_but_mormons.html

http://www.internaturalfoods.com/Cafix/Cafix.html

http://www.cajungrocer.com/cafe-du-monde-coffee-chicory-p-450.html?cvsfa=1338&cvsfe=2&cvsfhu=343530

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