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Light roasts have the most caffeine. Similar to regular cooking the longer coffee is roasted, the more caffeine (and other elements, CO2) are cooked out of it. Like performing a "reduction" in cooking. Medium to Dark roasts have more caramelized sugars lending that richer bolder flavor, but they will have invariably less caffeine. This difference in caffeine to most people will be a nelligible one, meaning you won't necessarily notice that your "french roast" doesn't wake you up like your light-roasted estate "single-origin" coffee does. Some people insist darker roasts wake them up - because of the "punch-you-in-the-face" flavor. I think that no coffee should ever "punch you in the face," it seems rude and improper roasting technique (i.e. Charbucks). But for the sake of science, Light Roasts are the Caffeine containing beans. It is possible to find a great light roast, where the salt compounds in the roast are almost gone - leaving only a bright, sweet (from natural sugar caramelization), delicate flavor on your palate. Also, use the proper coffee to water ratio for your brew or your coffee will come out weak no matter what you do.

In terms of brands, Shock Coffee says that their coffee is grown, blended, and roasted to maximize the caffeine levels. They sell beans and canned beverages and chocolate covered beans called "Shock-a-lots."

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