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Benzene, C6H6 is a non-polar simple covalent molecule with instantaneous induced dipole-Induced dipole interactions (Dispersion forces, Van der waal's forces of attraction). Water on the other hand is a polar simple covalent molecule with hydrogen bonding.

Water has hydrogen bonding because it's hydrogen atoms are attached to a highly electronegative atom (Oxygen) which pulls the bonding electrons so close to itself that the valence shell of the hydrogen atoms appear to be empty and ready to accept a lone pair of electrons from an oxygen atom of another water molecule. (In this case oxygen atoms have 2 lone pairs to contribute to hydrogen bonding.

Hydrogen bonding is far more stronger than dispersion forces and thus requires more energy to break. As such, water has a higher boiling point (100 0C) than benzene (80.1 0C) because more energy is required to break the forces of attraction holding the molecules of water together.

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Q: Explain why benzene C6H6 has a lower boiling point than water?
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