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Potassium permangante, being a very strong oxidizing agent, oxidizes both the Fe2+ ion and the oxalate ion. Redox reactions are shown below:

Oxalate oxidation: 2MnO4- + 16H+ + 5C2O42- ---> 2Mn2+ + 8H2O + 10CO2

Iron(II) oxidation: MnO4- + 8H+ + 5Fe2+ ---> Mn2+ + 4H2O + 5Fe3+

Moreover, if one needs to determine the exact percentage of oxalate and ferrous ions in solution, a titration is carried out using the permanganate, which will react with both the oxalate and ferrous ions. But, the carbon dioxide is liberated from the soution now, and zinc is added whch reduces the Iron(III) back to Iron(II). Another titration is then carried out using the permanganate, which gives a reading for the Iron(II) in solution only.

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Q: Ferrous oxalate reaction with potassium permanganate?
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Related questions

When KOH reacts with H2C2O4 what are the products?

The products of this reaction are potassium oxalate and water.


Why potassium oxalate is acidified before titration?

If the temperature is too low (below 55 degrees celsius), the interaction between the oxalate and the potassium permanganate will move too slow as to be used as a practical lab experiment. *** Above 60 degrees celsius, oxalate acid begins to decompose, so it's important to stay in this range.


How can you separate ferrous oxalate from titanium oxalate?

If you want to separate ferrous oxalate from titanium oxalate, you need to put them in an alkaline solution and introduce heat. They should break apart into their two respective oxolates.


Why do you have to warm the oxalate solution before performing titration?

because if the temperature is too low the interaction between the oxylate and potassium permanganate will move too slow?? why IDK


Is there a different between potassium oxalate and potassium acid oxalate?

sorrel salt: potassium hydrogen oxalate or potassium hydrogen oxalate, KHC2O4 (sal acetosella, salt of lemon). Here only one 'H' is replaced with 'K' in oxalic acid to get HOOC-COOK. Potassium oxalate is KOOC-COOK.


What is the chemical formula for ferrous oxalate?

Formula: FeC2O4


What is the formula for ferrous oxalate?

Fe(COO)2


Why is titration between potassium permanganate and sodium oxalate conducted slowly?

It is a reaction between negatively charged ions so they repel each other. For the reaction to work it is first heated, the Mno4- reacts with the Mn2+ produced to form Mn3+. The Mn3+ then reacts with the ethanedoate to form co2 and Mn2+. This is an example of autocatalysis.


Why do you have to warm the oxalate solution before perfoming the tritration?

I am not sure about this answer.oxalic acid is the strong is acid it need atleast 60 degree or more so that potassium permanganate can give the pink colour.


How can you prepare ferrous oxalate?

Add ferrous chloride solid to saturated aqueous solution of oxalic acid then to expel the HCl gas then saturated solution is allow to cool the crystals of ferrous oxalate settled down with in few minutes remove the excess liquid and get the dry compound.


What composition is Potassium oxalate?

KOOC-COOK.K2C2O4


What is the chemical formlula of potassium sulphate and oxalic acid?

K2C2O4 in chemical industry, alwasy Potassium Oxalate exist in Potassium Oxalate Monohydrate(K2C2O4.H2O), CAS NO.6487-48-5.