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I'm not quite sure what you mean, but georesistivity has been used to establish the presence and location of cavities. It is not very successful though because the void need only be mm wide, especially if filled with air, to show up.

Someyears ago a vibreiosis line(artifical seismicity) was undertaken across the cavernous Mendip Hills, in SW England, and local cavers asked to be told if it revealed any cavities. The survey company were interested but had to regret tha apart from commercial sensitivity of the data, their technicques would not show anything definite less than several hundred feet below ground, so would not detect caves.

Sensitive gravimetry might show up very large chambers.

Gorund-penetrating radar will work to a point, and was used in Gaping Gill (NW English, Pennine hills)to survey the very deep sediment covering the floor of the Main Chamber. It revealed the major current-bedding in the sediments, but whether it would show much in surface surveys I don't know. It depends on its penetration range and definition.

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