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Physically kept there? By gravity, same as all other atmospheric gases.

Chemically kept there in spite of its reactive nature? It's not, really. Atmospheric oxygen readily reacts chemically with other substances all the time. However, plants are continually pumping new oxygen into the atmosphere via photosynthesis in opposition to that trend, and the two processes roughly cancel each other out. (Or did, before combustion of fossil fuels started increasing carbon dioxide concentrations since the dawn of the industrial era.)

If it weren't for photosynthesis, a reactive gas like oxygen would not long remain a component of the Earth's atmosphere.

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