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Brass is a substitutional alloy. Due to the similar size of the two elements copper and zinc which make brass one can not fill the interstitial space between the other elements atoms. This means that it can not be interstitial.

The elements are however close in all the necessary aspects to form a substitutional alloy. They are relatively even in size, have the same crytal structure and have similar electronegativities. This allows one element to replace the other which in the case of brass where copper is the solvent, zinc atoms become a substitution for the copper atoms

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