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No. Vacuum has no temperature, and it cannot either cool anything down, nor heat anything up, by conduction or convection. An item in space that is in bright light or that is generating heat internally will become hot because there is no air to cool it, whereas an item in shade that is not generating internal heat will slowly lose heat by radiation (and perhaps sublimation of surface moisture) and become very cold.

Astronauts' space-suits have to be air-conditioned, not heated.

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