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Elemental oxygen exists as O2, which is a neutral molecule (neither anion or cation).

Oxygen, when in an ionic compound, such as FeO or Na2O, it is formally a divalent anion (i.e. O2-).

Oxygen can also hold a positive charge when it is tricoordinate, such as in an oxonium cation (common species in carbonyl chemistry).

Therefore, as the previous answer to this question stated, it depends on the form that oxygen takes in the compound.
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