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Starting with NaCl, Sodium and Chlorine have a large difference in electronegativity, which means in the polarity of water will be able to break the polar NaCl bond. In ethanol, C2H6O, there is enough difference in electronegativity between the Carbon and Oxygen for the polarity of the water molecule to break this bond. In CaCO3, it is the Carbon and Oxygen bonds again the break. This is far less soluble than the other two molecules, but the same reason still applies.

For recrystallisation, try something non-polar to wash your crystals, like hexane. If you were wanting to recrystalise the calcium carbonate, ice-cool distilled water would be fine and wouldn't drastically decrease your % yeild.

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Q: Suggest reasons why recrystallization from water would probably not be suitable procedure for purifying nacl caco3 c2h6o?
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