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The structure of solid BeCl2 is an unusual chain polymer with two chlorine atoms bridging between the Be atoms. The ClBeCl bond angle is less than tetrahedral, at 980 . It therefore achieves an octet of electrons and has an approximate hybridisation of sp3 .

The structure of liquid is dimeric with 2 chlorines bridging, Be does not achieve the octet in this.

In the gas the dimer persists up to around 900 0when it is fully dissociated into the linear Cl-Be-Cl monomer. This is linear as predicted by VSEPR.

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