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Assuming mass does not also increase, then density decreases if volume increases.

For example, let's say

Mass= 100 and Volume= 50

Density would = 2

Now, lets increase the volume.

Mass would still = 100, and let's increase the volume to 75.

Density would then equal 1.333...

2 is greater than 1.333.... so yes, density decreases as volume increases.

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