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The higher the altitude, the lower the pressure becomes. One way to think of this is that the lower levels of the atmosphere, near the surface, are being pressed down by the molecules stacked above them, all of them drawn by Earth's gravity. Similarly, water in the oceans exerts a higher pressure the deeper you dive.

Also, at the higher levels of the atmosphere, it is easier for molecules of lighter gases to achieve enough velocity to fly off into space.

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