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When a solution of sodium bromide is added to an acidified solution of Sodium bromate , bromine is liberated as given below:

6H+ + 5 Br- + BrO3- --> 3 Br2 + 3H2O

When a solution of sodium bromide is added to an acidified solution of Potassium bromate , bromine is liberated as given below:

6H+ + 5 Br- + BrO3- --> 3 Br2 + 3H2O

In the presence of acid, sodium and potassium ions have no effect on the rate of reaction (ref: Arthur I. Vogel, quantitative Inorganic analysis,page 369), extracted by CECRI- Electrochem Forum

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14y ago
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14y ago

DUE TO THE PRESENCE OF OH- IONS IN AQUEOUS Br,NaOH MIGHT BE OBTAINED.IT IS VERY DIFFICULT FOR NaBr TO FORM AS Br- CANNOT EASILY REPLACE Cl- DUE TO LARGER SIZE OF Br-.

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7y ago

Br2 + KCl ---> no reaction. Bromine is less active than chlorine, so it will not replace it. Therefore, there will tend to be no reaction in this case.

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7y ago

Any reaction because bromine is less reactive than chlorine.

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7y ago

Nothing. Chlorine is more reactive than bromine.

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10y ago

to produce KCL + BR

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Q: What happens when aqueous bromine is added to sodium chloride?
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