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Ethylacetate is more polar. IT has a carbonyl group, which means the more electronegative Oxygen is drawing electron density towards oxygen, hence leaves the carbonyl carbon to be delta positive, hence there is polarity between those atoms of the molecule, then there is the ethyl group attached to this same carbonyl carbon, which although there is a degree of induction due to the CH2CH3 somewhat pushing towards the the carbonyl carbon, yet again the oxygen attached draws more density away, than the ethyl aspect pushing in, hence on both fronts, the molecule is polar. NOW in comparison to petroleum ether, well, petroleum ether, is usually short chained alkanes, either pentane, hexane, and is a fraction of refined oil. THE UPPER LIGHTER FRACTION, and not to be compared to say an actual ether, such as diethyl ether. So on that basis, pet ether is non polar. NOW if you meant diethyl ether. ETHYL ACETATE is still more polar, as the ether has one oxygen between methylene groups, or perhaps two methyl groups. and yes, there is an electronegative difference between that oxygen and the carbon next to it, but an ether is flanked by two carbon groups, hence the polarity of the molecule is minimized.

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