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Step 1: Conceptual Introduction

Alkenes are hydrocarbons containing at least one carbon-carbon double bond (C=C) in their molecular structure. The geometry of the alkene molecule is determined by the arrangement of the atoms around the double bond, which imposes specific spatial constraints.

Explanation Block

The carbon atoms involved in the double bond in an alkene are sp² hybridized, meaning each carbon forms three sigma (σ) bonds and has one unhybridized p orbital. The unhybridized p orbitals on the two carbon atoms overlap sideways to form the π bond, which locks the molecule in a planar arrangement around the double bond. The bond angles around each sp²-hybridized carbon atom are approximately 120°, leading to a trigonal planar geometry.

Step 2: More Information

  1. Double Bond Rigidity:

    The π bond in the double bond restricts rotation, making alkenes more rigid compared to alkanes.

    This rigidity leads to the possibility of cis-trans isomerism in alkenes, depending on the substituents attached to the double-bonded carbons.

  2. Trigonality of the Carbon Atoms:

Each carbon atom in the double bond is attached to three groups, and these groups arrange themselves in a trigonal planar geometry to minimize repulsion between bonding pairs of electrons.

The planar structure ensures that the molecule exhibits specific chemical and physical properties, such as reactivity and optical behavior.

Step 3: More Information

  1. Overall Shape of the Alkene Molecule:

The shape of the entire alkene molecule depends on the substituents attached to the sp²-hybridized carbons.

For example, ethene (C₂H₄), the simplest alkene, has a completely planar structure, but larger alkenes can have portions that deviate from planarity due to single bonds beyond the double bond.

  1. Bonding and Orbital Overlap:

The sp² orbitals form sigma bonds with hydrogen atoms or other substituents, while the unhybridized p orbitals on each carbon atom overlap to form the π bond.

This bonding arrangement contributes to the unique chemical reactivity of alkenes, such as addition reactions.

Final Answer

The basic shape of an alkene around the carbon-carbon double bond is trigonal planar with bond angles of approximately 120°. This geometry arises from the sp² hybridization of the carbon atoms involved in the double bond.

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