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When you add ammonia solution to lead nitrate, the ammonia solution contains OH- ions and therefore, OH- ions will react with the lead nitrate rather than the ammonia.
The nitrate ion is a spectator ion so it can be disregarded as it doesn't take part in the reaction:

Pb+2 + 2OH- = Pb(OH)2 (s)


So Pb(OH)2 (s) is your white precipitate

Petar

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