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Copper Sulphate CuSO4

Since the question did not include Oxygen, the answer is Copper Sulphide (CuxSx)

If you have only Copper and Sulphur reacting the product is Copper Sulphide (CuS), not Copper Sulphate (CuSO4).

Copper Sulphide is made when Copper and Sulphur are heated together - the product is a black solid.

Copper Sulphate is produced when Copper is reacted either with sulphuric acid, or with a less reactive metal sulphate. Copper Sulphate is usually in the form of a blue solution but can be evaporated to produce a blue crystalline structure.

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