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There will not be any reaction .Both will remain togather in mixed form i.e.Na+ OH- and HSO3 ions in aquaeous solution

Dr. Pradhan

As a matter of fact there will be a reaction. Sodium Bisulfite (Sodium Hydrogen Sulfite) is a weak acid and Sodium Hydroxide is a Strong Base. Sodium Hydroxide will convert the Sodium Bisulfite to Sodium Sulfite (Na2SO3).

You can actually see the reaction take place as Bisulfite generally has a yellow tinge to it, when you add NaOH the yellow tinge disappears and the solution turns clear and colorless.

Chris D.

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