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Metallic bonding is between metal ions in a sea of delocalised electrons. In Aluminum, there are more delocalised electrons and the ions have a higher charge than Sodium. There is a greater force of attraction between the electrons of aluminum because the protons that are pulling on a 3+ ion are stronger than a 1+ ion. Since it requires more force to overcome these forces of attraction, Aluminum has the higher melting point.

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Q: Why does aluminum have a higher melting point than Sodium?
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