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A carbonate rock is known chemically as a carbonate salt. It has a metal cation ionically attracted to the carbonate anion. When a carbonate salt is placed in water, it will partially dissolve and some anions are formed. When acid is added, the carbonate reacts with the acid to form carbon dioxide and water. This means the anions that were in the water are no longer present. More of the salt dissolves in order to reach equilibrium and saturate the solution. However, the anions formed from that dissolution also react with the acid, and so forth until the entire rock (salt) is dissolved. The general reaction is as follows(where M is whatever metal is forming the rock with the carbonate):

MCO2(S) + 2H+(aq) --> M2+(aq) + H2O(l) + CO2(g)

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Q: Why does carbonate rocks react to acid?
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