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It is caused by the dispersion of sunlight by tiny water droplets, present in the atmosphere. The drops act like small prism. They refract and disperse the incident sunlight, then reflect it internally, and finally reract it again when it comes out of the rain drop. Due to the dispersion and internal reflection of light different colors reach the observer's eyes
When it rains the air gets moist. The moisture splits the light even after it stops raining.

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