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because both these elements are in the same group (7) of the Periodic Table and so each have 7 electrons in their outer electron shells.

An ionic compound is formed when one atom which preferentially looses electrons from its outer shell bonds through electrostatic attraction to another atom which preferentially gains electrons.

Some atoms will loose electrons in these sorts of chemical reactions because they have only a few electrons in their outer shell and it is energetically easiest for them to donate them in a reaction leaving the atom with a full outer shell, for example sodium has only one and looses it easily in reactions forming a positive sodium ion. Some atoms will accept extra electrons to form a complete outer shell, chlorine for example will accept one to become a negative chlorine ion. These two equal but oppositely charged ions will strongly attract each other.

Elements with 7 electrons each could only chemically bond by sharing an electron pair, the 7th from each atom combining to make a pair that both could share. This is called covalent bonding. This is what happens when chlorine and the other halogen elements form molecules, they go round in pairs Cl2, Br2, I2 etc bonded through the shared electron pair. A more interesting question is, why doesn't chlorine form a covalent compound with bromine?

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