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Remember that acid chlorides typically undergo nucleophilic substitution in which the partially positively charged carbon is attacked by nucleophile. Due to resonance(delocalization) in benzoyl chloride, the positive charge isn't concentrated in carbonyl C atom unlike in ethanoyl chloride but spreads over o and p positions in benzene ring. So, the carbonyl carbon in benzoyl chloride is less positive, less susceptible to nucleophilic attack and hence, less reactive.

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Q: Why is benzoyl chloride less reactive than ethanoyl chloride?
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