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It has got to do with the intermolecular (forces in between different atoms) forces. Iodine (I2) has weak intermolecular forces in between molecules, called a dispersion force. This force is very weak, resulting in lower boiling and melting temperatures. This happens for all covalent bonded non-metals.

Sodium Chloride, however, has a very strong intermolecular force. This is because they are Ionic (Metal and a Non-Metal). Ionic compounds are like a bar magnet, with the metal (Sodium) as the positive end and the non-metal (Chlorine) as the negative end. These form a 3D lattice Structure (a Cube Structure). The positive ends attract to the negative ends and vice versa.

This strong attraction means that when the substance is heated up, the molecules want to stay together. This results in a higher melting and boiling temperatures.

Note: Ionic forces are about 1000x stronger than dispersion forces

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Q: Why the melting points of sodium chloride and iodine are very different?
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