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In economic theory, Pareto efficiency refers to a situation where resources are allocated in the most efficient way possible, maximizing overall societal welfare. Externalities are costs or benefits that affect parties not directly involved in a transaction. The relationship between Pareto efficiency and externalities is that externalities can lead to market inefficiencies and prevent the achievement of Pareto efficiency. This is because externalities can result in a misallocation of resources and a failure to account for the full costs or benefits of a transaction, leading to a suboptimal outcome for society as a whole.

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