No, "friendless" is not a word. The correct term is "without friends" or "lacking friends."
He arrived in the new country and was friendless, but he soon began to settle in and meet people. His behaviour was so bad that people were disgusted at him and he found himself friendless.
I am friendless.
disabled, incapable, impotent, unable, friendless, powerless
abandoned, alone, solitary, forgotten, friendless, disconsolate, helpless
I was an unpopular and friendless student, avoided by all.
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St. Zita's Home for Friendless Women was created in 1890.
The word friend, meaning "close companion" is a noun. The word meaning "to befriend" is a verb. Adjectives include friendly and befriended, or friendless.
No, building is not a compound word.
The contraction (not a compound word) is doesn't.
Upwards is a compound word.