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Most substances expand as their temperature increases. Water is actually an exception to this rule, since, below 4oC, water actually contracts as it warms (and expands as it cools). This is why ice floats, because it's less dense than water. This is a very unusual thing in the world of chemistry, and only a very few substances exhibit this property. It has something to do with the rigidity of the bonds between the atoms and molecules. I can't fully explain it, and truth be told, I don't even understand it 100%.

Nevertheless, above 4oC, water acts "normally", i.e., it expands as it warms. The warmer it gets, the more volume it takes up. The expansion is not very significant in terms of the total volume of water.

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