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(Physics 10th Ed. version) the more energetic molecules are able to escape the liquid Changing liquid at one temperature to vapor at the same temperature, requires that the "latent heat of vaporization" be supplied from somewhere. This energy comes from the surface that is doing the evaporating. Temperature is the total energy of the molecules in a liquid. Where as in evaporation high energy molecules escape from liquid or any spread surface so total energy or heat contents of residual decreases causing cooling of residual liquid or spread surface.

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