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The electrons in a wire travel mostly along the outside of the wire and hence the bigger the circumference the more surface area decreasing the resistance. An analogy is a vat of water with a valve at the bottom. Imagine that the water is a store of electrons creating a potential or voltage. If you only open the valve a little, the water will flow out of the vat slowly and hence the higher the resistance. As you open the valve further there is less resistance and more water can flow.

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