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It is called a plasma discharge. It happens when a high voltage, pole top, air switch is opened under load and the current does not immediately stop but conducts through the air as the switch pole faces become further apart. Eventually the resistance of the air-gap overcomes the current flow and the plasma discharge extinguishes itself. These flash overs are hard on the contact points on the switch so long rods (called horns) are placed on the switch contacts so that as the contacts separate, the plasma discharge is drawn away from the contact and up the rods (horns) until the flash over stops. These types of switches are called horn gap switches.

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