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The two ways to charge a neutral body with static electricity is to dump a bunch of electrons onto it, thus making it negative, or attracting a bunch of electrons off of it, which will make it positive. There are several mechanisms that will allow us to do this. Just one example is to rub a balloon on your hair (if your hair is relatively dry) and you'll separate charges. This will cause the balloon to stick to your hair via the mechanism of static electricity.

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