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In potentiometry, no current flows because the measurement is based on the voltage difference between two electrodes in a solution, rather than the flow of charge. The system is designed to maintain a high impedance, allowing for the measurement of potential without drawing significant current, which could alter the concentration of ions in the solution and affect the accuracy of the measurement. Thus, potentiometric measurements focus on the equilibrium state of the electrochemical potential.

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What are two ways to identify the equivalent point in a titration?

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Direct potentiometry is a method of measuring the concentration of ions in a solution by directly measuring the potential difference between an ion-selective electrode and a reference electrode. It is a simple and rapid technique that is commonly used in the analysis of various ions in solutions.


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Potentiometry is a field of electroanalytical chemistry in which the potential of a solution is measured with no current flow; there are many different methods of doing this and structures of potentiometers in existence. It is used to determine the concentration of different analyte ions in solution. This can have many practical applications; potentiometry is used to determine the end-point of titrations, the amount of fluoride in drinking water, and the pH of solutions, among many other things.


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Platinum electrode is used as the indicator electrode in potentiometry titration to measure the potential difference between the indicator electrode and the reference electrode. It provides a stable and reproducible potential during the titration process, allowing for accurate determination of the equivalence point. Platinum electrodes are inert and do not participate in the redox reactions happening during the titration, making them suitable for a wide range of titrations.


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What are the working principles of potentiometry?

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