(insatiable means unable to be satisfied or quenched)
The movie star's appetite for debauchery seemed insatiable.
I had this insatiable curiosity to discover what was in that locked box.
People with an insatiable appetite for gossip often do not have compelling stories of their own.
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So- you are asking when to use 'when' in a sentence. When you are asking how to use when in a question, you are already using when in a sentence, because a question actually is a sentence. I like to use when in a sentence whenever I like.
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"I can use 'salutary' in a sentence!"