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In addition to horizontal and vertical trends in a periodic table,there is a diagonal relationship between certain sets of elements(Li and Mg, Be and Al, B and Si),that have upper left/lower right relative location in the Periodic Table.

These pairs of elements share similar size & electronegativity, resulting in similar properties.

Diagonal relationship occurs because crossing and desecnding periodic table have opposing effects. The diagonal relationship is due to increase in the charge in the ion and decrease in the size of ion as we move along the period. When we go down the group there will be decrease in the polarising power.These both cancel up when we move along the periodic table diagonally.

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