Charlotte is surprised to see Zachariah in the brig because she thought he was on leave, and she did not expect him to be confined in the brig instead of being free. This unexpected encounter makes her question what could have happened for him to end up in that situation.
Charlotte defended Zachariah because she believed in treating all crew members fairly and knew that Zachariah was innocent. She had a strong sense of justice and did not want to see anyone wrongly accused or punished. Additionally, Charlotte likely had a deeper connection or understanding of Zachariah's character that the others did not have.
It is Chapter 15 when he saves Charlotte. Also, she saw him when she was trying to cut away the foreyard.
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Charlotte initially views Zachariah with skepticism and fear due to his rough appearance and mysterious behavior. However, as she gets to know him better, she comes to see him as a kind and wise individual who becomes a trusted friend and ally throughout their journey.
Bulkington.
The only reason they would be surprised is because they're embarrassed (not surprised) to see you looking at them when they're caught off guard. They want to look good in front of girls, they are such jerks.
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Bulkington.
no
Pip was surprised to find a gun in Mr. Jaggers' office.