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Most organisms undergo a process called rigor mortis when they die. This is due to the fact that muscle movement requires energy (in the form of ATP). ATP is generated by respiration which can only be carried out by the mitochondria of living organisms. Therefore a dead organism cannot produce ATP so its muscles remain locked shut making it stiff. If you take a starfish out of water its skin will undergo a process called dessication which essentially means drying out that makes it harder and spikier than normal. Interestingly starfish are in the phlya echinodermata which translates literally as spiny skin.

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