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It is NOT a chemical reaction. Boiling is a physical reaction. When heat is applied to water in a pot, the hydrogen and oxygen molecules begin to get excited; they bounce around everywhere. The heat traps the oxygen molecules in bubbles, which go to the sides of the pot (following the path of least resistance). These bubbles then come to the surface, releasing oxygen and steam. Boiling is simply a phase change from a liquid to a gas.

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