No you can not. It is a starter Pokemon, that means it is unavailable for capture in the game. You can however, breed it with a Pokemon to get another Charmander, such as a ditto etc. Otherwise trade it from a friend.
As soon as you enter Mt Ember go right to find the Rockets.
at mt ember after fighting the rocket grunts and going in mt ember
they learn it at level 7.
Mt. Ember
The braille has no role in mt ember ignore it and just go to the ruby room and get the ruby.
Charmander (Starter)Charmeleon (Level up Charmander)Charizard (Level up Charmeleon)Ponyta (Kindle Road and MT. Ember)Rapidash (Kindle Road and MT. Ember)Moltres (Mt. Ember at Peak)Vulpix (Mansion Cinibar Island)Ninetales (Vulpix + Fire Stone)Eevee (Not Fire Type) (Celadon City Buliding)Flareon (Eevee + Fire Stone)Slugma (Mt. Ember)Magcargo (Mt Ember)Magby (Magmar Egg)Magmar (Mt Ember Grass Only)Houndoor (Altering Cave)Houndoom (Level up Houndoor)Entei (Available in wild if starter was bulbasaur)Ho-oh (Navel Rock)Requires trade:GrowlitheArcanineCyndaquilQuilavaTyphlosionTorchicCombuskenBlazikenNumelCameruptTorkoal
On top of Mt Ember.
he travels
CHARMANDER, learns ember at level 6 or 7
As soon as you enter Mt Ember go right to find the Rockets.
at mt ember after fighting the rocket grunts and going in mt ember
The emerald is not found on Mt. Ember in Pokémon FireRed. Ruby is found on Mt. Ember inside a cave.
level 8
lvl 7
the moves charmander learns go as: level 7- ember, level 13- metal claw
they learn it at level 7.
lvl. 7-10 Submitted by: Tyrex the Dragon