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the only ways to get a second masterball in Pokemon diamond and pearl is to migrate a Pokemon holding a masterball from another Pokemon game (you can repeatedly start new games and migrate the Pokemon holding masterballs), get a DS action replay and catch all of the unknown and show the crazy digger guy in the cave them and type in the code "cowfar" (it seriously works though it doesnt look at all like it) for unlimited masterballs, or just start a new game and give a friend you trust who also has Pokemon diamond or pearl the Pokemon with the masterball and trade them back after the new game. the easiest is action replay

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13y ago

What else can I help you with?