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Enter Socaleon Ruins east of Solaceon Town, then catch all 26 Unown forms. Then, go to the Ruin Maniac Cave (or Maniac Tunnel) on Route 214 and head west until you reach the end, where you'll encounter the last 2 Unown (! and ?).

You should also catch Hippopotas at Maniac Tunnel, since that's the only place where Hippopotas appear.

You can also show the Unown you catch to the guy in a house between Solaceon Town and the cave to get capsule decorations.

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