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First, you have to beat the Elite Four. After beating them, go to Mt. Coronet with some Pokemon that collectively know Surf, Waterfall, Rock Smash?, Rock Climb, and Strength. Get to the level below the snowing area with the waterfall. Go into the cave above the waterfall. There, you'll find a blue orb and a pink orb. Pick both of them up. Then, go to Celestic Town. There, you'll trigger an event involving Cynthia's grandmother. After looking at the pictures of Dialga and Palkia, you'll be able to catch both at Spear Pillar, as long as you have both orbs in your inventory. Spear Pillar is located at the very top of Mt. Coronet. You only need Rock Climb, Strength, and optionally Rock Smash to reach it.

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