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You can catch it but you will be forced to release it. Salamence requires a certain ammount of strategy and skill to capture. Try to obtain a Pokemon with a Fighting-type PokeAssist and use it on Salamence. You will also need a full blast of Plusle or Minun's electric PokeAssist if you want a chance of capturing Salamence. As said above, you cannot keep Salamence and you will not be able to capture it after the first time you encounter it in the Jungle Relic. You can capture when it is flying. That is the most easy way to capture it. To make it fly, draw a loop around it once.

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