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You can't catch Poliwrath; you can only catch Poliwhirl and then evolve it. Here are the places you can catch Poliwhirl in FireRed:

Routes 6, 22, 23, and 25, Four Island, Viridian City, Cape Brink, Cerulean Cave, Icefall Cave, and Ruin Valley (using the Super Rod).

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10y ago

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