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To get the first Master Ball you have to get to the boss's office in the team aqau base where it will be one of the four pokeballs there (the other three are two Electrodes and a nugget). The only other way is to trade or have all numbers match while doing the lottery in Lilycove City department store.

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Masterballs on Pokemon Emerald?

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How do you hack into Pokemon emerald so you can buy masterballs?

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Well, this is if you have Pokemon Emerald and LeafGreen AND you know how to duplicate in Emerald, then follow these steps. It'll take some time though. (You need a MasterBall in Emerald too.)1. In Emerald, make ANY Pokemon of yours HOLD a masterball.2. Then, duplicate that Pokemon the number of masterballs you want. (EX. I want 10 masterballs, so I duplicate it nine times. {remember, it's counting the one you already have})3. Take the masterballs from the multiple Pokemon.4. trade Pokemon that are holding masterballs to leafgreen.Sorry I didn't give you UNLIMITED but that's all I have. Oh and also, don't use ALL your masterballs, then you can't duplicate any more. So I hope this helped!!Materials:-two Pokemon games-two game consoles-trading cable


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