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Moltres is located on One Island, which you will reach after receiving your seventh badge from Cinnabar Island's gym. Once on One Island, walk as far east as the island will let you and then surf northeast. Continue heading north until you come to some water on the north west edge of the Ember Spa. Surf north and you will find Mt. Ember. Moltres is at the top of the mountain.It is obvious that using a Master Ball would be the easy choice in this situation. But, if you are a serious trainer, it is advised that you do not use your Master Ball to catch Moltres because there are better and harder Pokemon to catch (e.g., Lugia, Ho-Oh, Mewtwo, Mew, Lugia, Deoxys, etc). A common alternative choice is to lower Moltres's HP as low as possible without causing it to faint, and then throwing Ultra Balls at it until you successfully catch it. This process can take a while and will need plenty of funds for Ultra Balls and Hyper Potions. It is also a good idea to save your game before attempting to do this for fear of Moltres fainting, your own Pokemon fainting, or running out of Ultra Balls.
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