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You can't catch Phione but you can receive on from an egg because Manaphy+Ditto=Phione Egg. In other words, put Manaphy and Ditto in the Day Care Center and eventually there will be a Phione Egg.

P.S. YOu can catch/receive a Manaphy by:

Pokemon Ranger

Pokemon Ranger Shadows of Almia

Pokemon Ranger Guardian Signs

Pokemon Event (if any)

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14y ago

What else can I help you with?