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After beating Rayquaza, talking to Medicham, visiting Lombre and Whiscash, and getting HM Dive, you go through Solar Cave. Eventually, after Spinda shows up, you'll eventually go through Fiery Field, Lightning Field, Northwind Field, and Mt. Faraway to beat Entei, Raikou, Suicune, and Ho-oh. After you recruit Ho-oh when you meet it again, Western Cave will be unlocked.

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